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51.
Introduction Data mining (SHAO and YU, 2003) is a new kind of technique developed with database and artificial intelligence in recent years, which processes the data in the database to abstract the im- plied and pre-unknown, but potentially useful information and knowledge from large amounts of incomplete, noisy, blurring and stochastic data. For data mining, data purging is an important link beforehand that includes eliminating noise, making up lost domain, and deleting ineffective data, as… 相似文献
52.
Edith L Gego P. Steven Porter John S. Irwin Christian Hogrefe S. Trivikrama Rao 《Pure and Applied Geophysics》2005,162(10):1919-1939
Airborne fine particulate matter across the United States is monitored by different networks, the three prevalent ones presently being the Clean Air Status and Trend Network (CASTNet), the Interagency Monitoring of PROtected Visual Environment Network (IMPROVE) and the Speciation and Trend Network (STN). If combined, these three networks provide speciated fine particulate data at several hundred locations throughout the United States. Yet, differences in sampling protocols and samples handling may not allow their joint use. With these concerns in mind, the objective of this study is to assess the spatial and temporal comparability of the sulfate, nitrate and ammonium concentrations reported by each of these networks. One of the major differences between networks is the sampling frequency they adopted. While CASTNet measures pollution levels on seven-day integrated samples, STN and IMPROVE data pertain to 24-hour samples collected every three days. STN and IMPROVE data therefore exhibit considerably more short-term variability than their CASTNet counterpart. We show that, despite their apparent incongruity, averaging the data with a window size of four to six weeks is sufficient to remove the effects of differences in sampling frequency and duration and allow meaningful comparison of the signals reported by the three networks of concern. After averaging, all the sulfate and, to a lesser degree, ammonium concentrations reported are fairly similar. Nitrate concentrations, on the other hand, are still divergent. We speculate that this divergence originates from the different types of filters used to collect particulate nitrate. Finally, using a rotated principal component technique (RPCA), we determined the number and the geographical organization of the significant temporal modes of variation (clusters) detected by each network for the three pollutants of interest. For sulfate and ammonium, the clusters’ geographical boundaries established for each network and the modes of variations within each cluster seem to correspond. RPCA erformed on nitrate concentrations revealed that, for the CASTNet and IMPROVE networks, the modes of variation do not correspond to unified geographical regions but are found more sporadically. For STN, the clustered areas are unified and easily delineable. We conclude that the possibility of jointly using the data collected by CASTNet, IMPROVE and STN has to be weighed pollutant by pollutant. While sulfate and ammonium data show some potential for joint use, at this point, combining the nitrate data from these monitoring networks may not be a judicious choice. 相似文献
53.
Spatial character of the gaseous and particulate state compound correlation of urban atmospheric pollution in winter and summer 总被引:1,自引:0,他引:1
XU Xiangde SHI Xiaohui XIE Lian DING Guoan MIAO Qiuju MA Jianzhong ZHENG Xiangdong 《中国科学D辑(英文版)》2005,48(Z2)
The spatial/temporal variation information of atmospheric dynamic-chemical processes at observation site points of the "canopy" boundary of Beijing urban building ensemble and over urban area "surface", as well as the seasonal correlation structure of the gaseous and particulate states of urban atmospheric pollution (UAP) and its seasonal conversion feature at observation points are investigated, using the comprehensive observation data of the Beijing City Air Pollution Observation Experiment (BECAPEX) in winter and summer 2003 with a "point-surface" combined research approach. By using "one dimension spatial empirical orthogonal function (EOF)" principal component analysis (PCA) mode, the seasonal change of gaseous and particulate states of atmospheric aerosols and the association feature of pollutant species under the background of the complicated structure of urban boundary layer (UBL) are analyzed. The comprehensive analyses of the principal components of particle concentrations,gaseous pollutant species, and meteorological conditions reveal the seasonal changes of the complex constituent and structure features of the gaseous and particulate states of UAP to further trace the impact feature of urban aerosol pollution surface sources and the seasonal difference of the component structure of UAP. Research results suggest that in the temporal evolution of the gaseous and particulate states of winter/summer UAP, NOx, CO, and SO2 showed an "in-phase" evolution feature, however, O3 showed an "inverse-phase" relation with other species,all possessing distinctive dependent feature. On the whole, summer concentrations of gaseous pollutants CO, SO2, and NOx were obviously lower than winter ones, especially, the reduction in CO concentration was most distinctive, and ones in SO2 and NOx were next. However, the summer O3 concentration was more than twice winter one. Winter/summer differences in PM10and PM2.5 particle concentrations were relatively not obvious, which indicates that responses of PM10 and PM2.5 particle concentrations to the difference of winter/summer heating period emission sources are far less distinctive than those of NOx, SO2, and CO. The correlation feature of winter/summer gaseous and particulate states depicts that both PM10 and PM2.5 particles were significantly correlated with NOx, and their correlations with NOx are more significant than those with other pollutants. Through PCA, it is found that there was a distinctive difference in the principal component combination structure of winter/summer PM10 and PM2.5 particles: SO2 and NOx dominated in the principal component of winter PM10 and PM2.5 particles; while CO and NOx played the major role in the principal component of summer PM10 and PM2.5 particles. For winter/summer PM10 and PM2.5 particles, there might exist the gaseous and particulate states correlation structures of different "combinations" of such dependent pollutant species. Research results also uncover that the interaction processes of gaseous and particulate states were also related with the vertical structure of UBL, that is to say, the low value layer of UBL O3 concentration was associated with the collocation of atmospheric vertical structures of the low level inversion,inverse humidity, and small wind, which depicts summer boundary layer atmospheric character, i.e.the compound impact of the dependent factor "combination" of wind, temperature, and humidity elements and their collocation structure on the variations of different gaseous pollutant concentrations. Such a depth structure of the extremely low value of O3 concentration in the UBL accords with its "inverse-phase" relation with other gaseous pollutant species. The PCA of meteorological factors associated with PM10 and PM2.5 concentrations also reveals the sensitivity of PM10 and PM2.5 concentration to the combinatory feature of local meteorological conditions. 相似文献
54.
Grayna Ceglarska-Stefaska Katarzyna Zarbska 《International Journal of Coal Geology》2005,62(4):211-222
The paper reports the results of experiments concerning the sorption/desorption processes, observed under laboratory conditions, in two types of coal extracted from operational coal-mines in Poland, using CH4 and CO2 to observe their relative inter-reaction with the coal samples when introduced in varying proportions and conditions. Numerous studies concerning the sorption/desorption phenomena have described the operational mechanisms and the relationship of mine gases to the organically-created coal-body in mines. The differences in the behaviour of certain gases is twofold: firstly the essentially different characteristics of CO2 and CH4, and secondly the structure of the coal-bed itself: its degree of metamorphism and content of macerals. From the results yielded, it was observed that the divergence of the isotherms of sorption of CH4 and other gases in comparison with the isotherms of sorption of CO2 and a CO2/CH4 mixture differed and that the curve on the sorption isotherm was more clearly distinct after the introduction of CO2 molecules to the system: coal with a higher degree of metamorphism—CH4, which is closely related to the rigidity of the structure according to the level of metamorphism. Since coals with higher carbon content exhibit lower molecular bonding than low-carbonised coals, the characteristic feature of the bonds in the first case is their mobility. Knowledge of the physical and chemical properties of hard coals, as well as their interaction with mining gases, is of great use in solving problems concerned with the extraction of methane from mines or its storage in goafs. 相似文献
55.
以祁连山排露沟流域青海云杉林为研究对象,研究了海拔梯度上土壤肥力因子的分布特征及变化规律,并运用主成分分析法对青海云杉林土壤肥力状况进行了评价。结果表明:(1)研究区土壤呈碱性,pH值均大于8.0;高海拔地区(3 300 m)含水量达到过饱和状态,各土层含水量均大于100%;随海拔升高,全氮含量呈增大趋势,全钾含量呈减小趋势,而全磷含量呈先减小后增大趋势;不同海拔梯度速效磷含量差异不显著(P>0.05),海拔3 300 m处速效钾含量显著高于其他海拔段(P<0.05)。(2) 不同海拔梯度下土壤有机质、全氮、全磷、全钾、速效磷和速效钾含量都有明显的“表聚效应”,其中3 300 m处0~10 cm土层有机质含量高达325.93 g·kg-1,是本海拔段其他土层的1.6~1.8倍,是同土层其他海拔段的1.3~2.0倍。(3) 土壤肥力因子间关系密切,土壤含水量与有机质、全氮呈极显著正相关关系,与土壤容重、pH和全钾呈极显著负相关关系,土壤养分含量之间存在不同程度的显著正相关关系。(4) 不同海拔梯度土壤肥力质量为:3 300 m>3 200 m>3
100 m>3 000 m>2 900 m。 相似文献
56.
类型丰富、时空分辨率高的海洋探测数据,为信号分解和机器学习算法的应用提供了可能。本文针对如何建立有效的海温预测模型这一问题,使用高时空分辨率的海表温度(SST)融合产品,引入信号处理领域的集合经验模态分解(EEMD)和机器学习领域的自回归积分滑动平均模型(ARIMA)。首先利用最适于分解自然信号的EEMD方法,将海温数据分解成多个确定频率的序列;再利用ARIMA分别对各个频率的序列进行预测,最后将各个序列的预测结果进行组合。该方法在丰富数据的支撑下,比以往直接使用海温数据所建立的预测模型精度更高,为更好地进行海温预测提供了新方法。 相似文献
57.
Frequency analysis of nonstationary annual maximum flood series using the time‐varying two‐component mixture distributions 下载免费PDF全文
The most popular practice for analysing nonstationarity of flood series is to use a fixed single‐type probability distribution incorporated with the time‐varying moments. However, the type of probability distribution could be both complex because of distinct flood populations and time‐varying under changing environments. To allow the investigation of this complex nature, the time‐varying two‐component mixture distributions (TTMD) method is proposed in this study by considering the time variations of not only the moments of its component distributions but also the weighting coefficients. Having identified the existence of mixed flood populations based on circular statistics, the proposed TTMD was applied to model the annual maximum flood series of two stations in the Weihe River basin, with the model parameters calibrated by the meta‐heuristic maximum likelihood method. The performance of TTMD was evaluated by different diagnostic plots and indexes and compared with stationary single‐type distributions, stationary mixture distributions and time‐varying single‐type distributions. The results highlighted the advantages of TTMD with physically‐based covariates for both stations. Besides, the optimal TTMD models were considered to be capable of settling the issue of nonstationarity and capturing the mixed flood populations satisfactorily. Copyright © 2016 John Wiley & Sons, Ltd. 相似文献
58.
59.
在分析比较经验模态分解(EMD)、小波变换(Wavelet)和独立分量分析(ICA)优缺点的基础上,提出一种新的EMD-Wavelet-ICA耦合模型。该模型充分利用了EMD的自适应性,对原始信号进行分解获得不同频率的模态函数(IMF),采用标准化模量的累计均值对IMF进行尺度划分;进而分别采用Wavelet和ICA对高频和低频IMF进行降噪,将降噪后的IMF进行多尺度重构,获得降噪后的信号;采用信噪比、标准差、偏差和相关系数等指标对降噪效果进行评价。仿真数据和GPS坐标序列的处理结果表明:与EMD模型和EMD-ICA模型相比,新模型的标准差、偏差均有不同程度的减小;信噪比和相关系数有一定程度的增大,可以获得更好的降噪效果。 相似文献
60.
Logistic判别模型在强降水预报中的应用 总被引:2,自引:2,他引:0
利用Logistiv判别模型进行强降水预报,并设计3种方案进行对比分析。方案1直接使用14个影响因子进行判别预报,受因子共线性作用及噪音信号影响,虽然拟合效果较好,但预报效果明显下降。方案2对14个影响因子进行主成分分析,利用前6个主成分建模,虽然拟合效果较方案1降低,但由于消除了因子共线性作用以及噪音信号影响,预报效果较方案1提高。方案3运用Bootstrap抽样技术得到符干样本并建模计算模型参数,打乱了原有时间序列中的波动,仪保留平稳信息,拟合自由度进一步降低,导致拟合效果较方案案2下降,但预报效果却是3种方案中最好且最稳定的。在上述研究基础上,利用欧洲中心数值预报模式的预报场资料,建立基于Logistic判别模型的强降水客观预报系统,并在中央气象台业务运行。2013和2014年连续两年汛期预报检验结果表明,概模型对强降水预报的TS评分高于数值模式本身,具有一定的业务参考价值。 相似文献